Chloride stress corrosion cracking clscc is one the most common reasons why austenitic. Chlorideinduced stress corrosion cracking of powder metallurgy duplex stainless steels a. If the atmosphere contains halides this can leave any stainless steel susceptible to chloride stress corrosion cracking ciscc. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and. A great concern for the longterm integrity of canisters located near the coastline is chlorideinduced stress corrosion cracking of austenitic stainless steels 3 45. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment.
It requires a susceptible material and, depending on the material, sufficient levels of. Chloride stress corrosion cracking is a well known form of scc, typically caused by inadvertently contaminating equipment with chlorides. Chloride stress corrosion cracking in austenitic stainless steel. Laitinen 1 helsinki university of technology, laboratory of engineering materials, puumiehenkuja 3, fin02150, espoo, finland. Polyamide is sensitive to degradation by acids and polyamide mouldings will crack when attacked by strong acids.
It attacks austenitic stainless steel components in the petrochemical industry. Diagnostics of chlorine induced stress corrosion cracking. Chloride stress corrosion cracking in austenitic stainless. Ciscc is one of the most common reasons for steel deterioration. Thermowells can breathe during normal operation as vessels heat up and cool down, drawing in the external atmosphere through non gas tight fittings. Understanding the risk of chloride induced stress corrosion. Because austenitic stainless steels are prone to chlorideinduced stress corrosion cracking ciscc, the concern has been raised that scc may significantly. Chloride induced stress corrosion cracking ciscc in. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Stress corrosion cracking facts and how to reduce the risk.
Pdf chloride induced stress corrosion cracking of type. One of these challenges is chloride induced stress corrosion cracking ciscc. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Chlorideinduced stress corrosion cracking of powder.
Scc usually occurs in certain specific alloyenvironmentstress combinations. To understand the mechanisms behind chlorine induced stress corrosion cracking ciscc in 304 stainless steel, synchrotron high energy xrays were use. For example, the fracture surface of a fuel connector showed the progressive growth of the crack from acid attack ch to the final cusp c of polymer. The corrosion initiated by the deliquescence of atmospheric water coupled with susceptible materials and residual stress can lead to stress corrosion cracking. Stress corrosion cracking scc is the cracking induced from the combined influence of. Chloride induced stress corrosion cracking of type 304 and. The stainless steel canister inside a dry cask storage system dcss is at risk for chlorine induced stress corrosion cracking scc, especially near welds and at storage sites exposed to high humidity. Chloride induced stress corrosion cracking of stainless.
The use of material susceptible to stress corrosion cracking scc. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater. Chloride stress corrosion cracking in austenitic stainless steel is. Pdf chloride induced stress corrosion cracking of type 304 and. In situ synchrotron xray tomography of 304 stainless. Chlorideinduced stress corrosion cracking of used nuclear fuel. Pdf chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in. Chloride induced stress corrosion cracking of type 304 and 304l stainless steels in air masami mayuzumi, taku arai and koichiro hide. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and incurs plant downtime. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Chemicals other than water, like ammonia, can induce subcritical crack propagation in silica glass, but they must. There are several types of stress corrosion cracking scc, for example, chloride induced scc and h 2 s induced scc. As was noted above, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Chloride stress corrosion cracking inspectioneering.
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